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Cake day: June 29th, 2023

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  • Yes, on the rare occasion I cook meat. Too unpracticed otherwise. I originally got one because I’m colorblind and was scared of undercooking red meat and tired of eating leather. As a bonus, I used it to get the temperature right when I got into fancier teas and inadvertently trained myself to judge the temperature of water pouring into my mug by the sound it makes within a couple °C, which is kinda neat. Now, if I could figure out how to do something similar so I stop overcooking food, that’d be grand…


  • I know that this is partially a joke, but I was trying to figure out what kind of lab would be done to produce chloroform that would be appropriate for students (recent OSHA crackdown on chloromethanes notwithstanding)… haloform reaction I suppose? Is that a common teaching lab experiment?


  • My mom took my little brother to participate in a child psych study like this when he was a toddler (mom had some ties to the university). It was a very similar experiment with skittles as the prize. My brother sat staring glumly at the candy the whole time. The test administrator was increasingly enthusastic with praise after each round right up until the end when she congratulated him and said that he could have the whole bag. He said “no thanks” and ran back to mom crying because he was told there would be candy but they only had skittles, which he very much did not like (and for that matter still doesn’t). The administrator was apparently embarrassed and told my mom that she thought that all kids liked skittles…



  • According to my buddy who worked for Dow, part of these “savings” apparently was taking a hatchet to their R&D segment with a bunch of spray-and-pray layoffs (apparently a common happening these days). I realize Dow is mostly commodity chemicals these days which is much more preservative in nature than other segments of the chemical industry, but even so it sounds like they are killing any hope of competing with new technologies and moving to the “squeeze as much as possible out before it goes tits up” stage.





  • If I stood up straight, my eye level was above the window. Also, glove boxes. The shorter group members could use platforms to raise their height but had trouble reaching the corners, while I had to do a mix of taking an uncomfortably wide stance and slouching. I wish they had been more suitable for my height… I thought everything would be better with taller hoods in my current workplace, but all they did was extend the sash to the floor.


  • I got one because I was intrigued by its lead rotation, but I found that it really didn’t rotate the lead enough while I wrote. I kept having to rotate the barrel manually to keep a thin line like I do for every other mechanical pencil, and then would get annoyed every time the clip came around to brush my hand. I’ve been wondering if I’m doing something wrong, or if Japanese just uses more shorter strokes. Do you also like it when writing English?


  • Arsenic is a classic murder poison. It’s been known since anciemt times, though possibly unsuited to your onset requirement. Acute poisoning by ingestion is generally within a few hours, but if your character sustains lower doses over time, you could probably draw out the timeline to whatever you wanted. It would be obvious that the character is unwell during this time, but the symptoms aren’t super specific and could be confused with e.g. food poisoning.

    Or just invent a mushroom like others said. The toxins are diverse enough that I doubt anyone would be too upset if you tuned it exactly to your timeline and desired symptoms.







  • The intended joke is that hypervalent iodine compounds like Dess-Martin periodinane flip between different oxidation states like you often see for transition metals. As an example, the mechanism usually drawn for oxidations by DMP is similar to those drawn for PCC/Jones reagent, where the electrons removed from the substrate are “banked” at the metal center. Obviously, redox chemistry is not at all limited to transition metals, but I am often surprised at iodine’s propensity to engage in it. A lot of research over the past decade or two has also developed redox catalysis with these reagents, reactivity which is commonly (though again not always) the purview of transition metals.